Hold your knife at a 45-degree angle and slice the chicken against the grain into thin pieces, about ⅛-inch thick. Add the chicken to a medium bowl with the soy sauce, water, sugar, baking soda, salt, olive oil, and white pepper. Mix well, then add the starch and toss again to coat.
Set it aside in the fridge to marinate for 15 minutes.
Prepare the aromatics and shiitake
Finely mince the garlic and julienne the ginger. Slice the scallions into small rounds, keeping the white and green parts separate. Slice the shiitake mushrooms into strips.
Prepare the napa cabbage
Trim about ½ inch from the bottom of the napa cabbage and remove any bruised or dirty outer leaves. Quarter the cabbage and cut out the hard core at the bottom.
Separate the thicker stems from the leafy parts. Cut the stems into smaller bite-size pieces and the leafy parts into larger pieces. Rinse and drain well, keeping the stems and leaves separate.
Make the sauce
In a small bowl, combine the sauce ingredients from soy sauce to Chinese rice wine, if using. Stir well and set aside.
Sear the chicken
Preheat a large sauté pan or wok over medium heat until it feels quite warm. Add 1 tbsp oil and swirl it around the pan.
Add the chicken, turn the heat up to medium-high, and quickly spread the pieces into a single layer. Pan-fry without moving them until the bottom turns golden brown, about 2 to 3 minutes. Flip and sear the other side for 1 to 2 minutes, or until the chicken is cooked through and golden on the outside.
Transfer the chicken to a plate and set aside.
Sauté the aromatics
Use the same pan and add 1 tbsp oil. Add the garlic, ginger, and white scallion parts with a pinch of salt. Sauté over medium heat until fragrant, about 15 seconds.
Cook the cabbage stems
Turn the heat up to medium-high. Add the napa cabbage stems and season with 2 pinches of salt. Stir-fry until the stems begin to turn tender, about 2 minutes. If the pan feels dry, add another ½ tbsp oil.
Add the cabbage leaves and shiitake
Add the leafy parts of the cabbage, shiitake mushrooms, and ½ tbsp chicken broth to lightly deglaze the pan. Toss everything together, then lower the heat to medium and cover with a lid.
Cook until the cabbage wilts slightly but still holds its shape, about 3 minutes.
Add the chicken and sauce
Uncover and turn the heat back up to medium-high. Return the chicken to the pan. Stir the sauce again, then pour it into the skillet.
Toss everything together for about 1 minute, until the sauce lightly coats the chicken and vegetables. Turn off the heat.
Garnish and serve
Transfer to a large serving plate. Garnish with the green scallion parts and drizzle with toasted sesame oil. Serve hot or at room temperature.
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Notes
Make-ahead: Slice and marinate the chicken up to 1 day ahead. You can also cut, rinse, and dry the napa cabbage well, then store it in the crisper drawer overnight.
Storage: Store leftovers in an airtight container in the fridge for up to 4 days.
Reheat: Microwave on high for 1 minute, stir, then heat for another 30 seconds to 1 minute, or until warmed through.